More espionage and adventure are in store for Chuck Bartowski (Zachary Levi), an ordinary computer geek turned CIA lynchpin, in the third season of this hit series. As Season 2 drew to a close, Chuck uploaded a new version of Intersect into his brain. Now he possesses a whole new set of skills -- all the better to battle the sinister CIA splinter group Fulcrum. Yvonne Strahovski, Adam Baldwin and Joshua Gomez co-star.

1. Chuck vs. the Pink Slip - With the upgraded Intersect, Chuck wants to become a real spy, but he fails his training, so he is fired instead. Chuck needs to find a way back into spy business. 4.38 stars (Dale-4, David-4.75)

2. Chuck vs. the Three Words - When Carina is back in town, Chuck flashes on her fianc, identifying him as an arms dealer, so Chuck is assigned to a new mission with Sarah, Carina and Casey, but his emotions come in the way. Meanwhile, Big Mike is back to manage the store, and Morgan falls for Carina. 4.5 stars.

3. Chuck vs. the Angel de la Muerte - Premier Alejandro Goya, a dictator who wants to open his country for democratic elections, is treated at Westside Medical Hospital, where Captain Awesome and Ellie work. The team is assigned to protect Goya during his stay, while Chuck has to gain some inside medical information about Goya by using Devon. 4.63 stars (Dale-4.75, David-4.5)

4. Chuck vs. Operation Awesome - After Captain Awesome is kidnapped, he is questioned by Ring-operative Sydney Prince, who equips him with a communication device of the Ring and releases him in order to recruit him, as she mistakes him for the spy in the family. General Beckman wants to use Devon to get to Sydney Prince, so the team needs to coach Devon in this new situation. Meanwhile, Big Mike promotes Morgan to Assistant Manager. 5 stars

Disc 1: 4.63 Stars
Season 3 (Disc 1): 4.63 stars
Collection (Season 1-2): 4.41 stars