After finally tying the knot with Sarah, thwarting Volkoff Industries and leaving the CIA, Chuck must adjust to life as a newlywed and a private spy. There are also complications in store for the always bumbling Morgan, who is the new Intersect.

Rated NR 3 hours 35 minutes 2011

1. Chuck vs. the Zoom - Chuck must adjust to his new life as a business owner and being a spy without the Intersect in his head or the support of the CIA. Carmichael Industries' first mission is a rich thief Jean Claude and a conning investor, Roger Bale, who has stolen money from some of the world's most dangerous people. In the mean time Morgan helps Chuck with a special surprise for Sarah. Back in the Buy More, Jeff and Lester have taken things to another level with their latest scheme. 4.13 stars (Dale-4, David-4.25)

2. Chuck vs. the Bearded Bandit - The team takes on a missing persons case and have to establish themselves as Carmichael Industries in the face of a rival security firm led by Gertrude Verbanski. Meanwhile Morgan adjusts to being the intersect and Chuck being his handler. Also the Buy More finds a new and unlikely spokesperson who helps to drum up business. 4.25 stars (Dale-4, David-4.5)

3. Chuck vs. the Frosted Tips - Chuck has some fears about Morgan having the intersect and it going to his head. Elsewhere Sarah helps Casey navigate his relationship with Gertrude Verbanski. And in the meantime Devon is spending his paternity leave with baby Clara at home but quickly finds it unexciting and that leads him to the Buy More where he makes a startling revelation about Jeff and Lester. 4.13 stars (Dale-4, David-4.25)

4. Chuck vs. the Business Trip - Chuck and Sarah attend a Buy More sales convention where they also have to uncover an assassin among the employees, whose mission is to take down the new intersect. Meanwhile Morgan has to deal with the consequences of having the intersect. And at the Buy More, Jeff begins to show a different side of himself. 4.5 stars.

5. Chuck vs. the Hack Off - Chuck turns to Verbanski for help tracking a computer virus; while Lester and Jeff's relationship is complicated by a new Buy More employee. 4.63 stars (Dale-4.5, David-4.75)

Disc 1 - 4.33 stars
Season 5 (Disc 1) - 4.33 stars
Collection (Season 1-4): 4.51 stars